ASA Southern Branch 2007 Annual Meeting
February 4-6, 2007
Mobile, AL

Monday, 5 February 2007 - 2:45 PM

Effect of phosphate amendments on leaching of Pb in selected shooting range soils.

Abioye O. Fayiga, Uttam Saha, and Lena Ma. University of Florida, Gainesville, FL 32611

A cost effective way to prevent and minimize lead migration and subsequent environmental pollution is through immobilization of the contaminant. In this study phosphate rock and phosphoric acid was used to immobilize lead in soil columns.

Phosphate was applied at a molar ratio of P/Pb 4:1 with two-thirds of the P supplied by PR and one-third by PA. Four shooting range soils were incubated for 18h overnight in soil columns. Leaching/percolation was done in two stages with TCLP and SPLP fluids respectively. Even though there was a >90% decrease in Pb leached from all phosphate treated soils, the treatment effectively reduced TCLP Pb to below 5 mg/L in rifle 1 and rifle 3.    Soil properties such as clay, total Fe and total P contributed significantly to the reduction in TCLP-Pb leached after 18h of incubation even  though clay content was the only significant predictor at α= 0.05.  There was initially a fast release of Pb with TCLP fluid followed by a slow release in untreated shooting range soils. The metal release was positively correlated to the pH of the leachates suggesting a proton-induced mineral desorption and dissolution. Addition of phosphate sources changed the pattern of release probably due to immobilization of lead in the soil.


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