Sunday, 24 June 2007

A Comparison of Lime Requirement Tests on New York Soils.

Kevin A. Dietzel, Renuka Rao, and Quirine Ketterings. Cornell University, Department of Crop and Soil Sciences, 803 Bradfield Hall, Ithaca, NY 14853

Currently, lime requirements for New York (NY) soils are derived from the actual soil pH, target pH and exchange acidity determined by a barium chloride (BaCl2) titration. The latter analysis is time-consuming and generates toxic waste. Our objective was to compare the accuracy of the Mehlich buffer with half the BaCl2 replaced with calcium chloride (CaCl2), the modified Mehlich buffer (CaCl2 instead of BaCl2), Shoemaker-McLean-Pratt (SMP) buffer, and Sikora buffer in predicting lime needs for NY agricultural soils. Twenty-two soils were collected from major agricultural areas in NY. The soils ranged in initial pH from 4.1 to 6.4 and in exchangeable acidity from 6.5 to 31.0 cmolc kg-1. Organic matter levels ranged from 16 to 73 mg kg-1 and Morgan extractable Al varied from 7 to 117 mg kg-1. Soils were incubated in the dark at 21 degrees C for 12 weeks with CaCO3 added at 0, 1/3, 2/3, 1, 1 1/3, and 2 times the lime required to reach pH 7.0 (based on the BaCl2 titration). Actual CaCO3 additions ranged from 0.18 to 1.64 g 100 g soil-1. One week out of three the perforated lids were removed to allow soil drying, followed by rewetting to between 25 and 37% moisture. Following the incubation, soils were analyzed for pH to determine the lime requirement for each of the individual soils and Morgan extractable Al to determine the amount of CaCO3 needed to neutralize soil Al. The results of the study will be presented and discussed.

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